Tag Archives: silicon

New kind of “tandem” solar cell developed: MIT Research

Researchers combine two types of photovoltaic material to make a cell that harnesses more sunlight.

By David Chandler


 

CAMBRIDGE, Mass–Researchers at MIT and Stanford University have developed a new kind of solar cell that combines two different layers of sunlight-absorbing material in order to harvest a broader range of the sun’s energy. The development could lead to photovoltaic cells that are more efficient than those currently used in solar-power installations, the researchers say.

The new cell uses a layer of silicon — which forms the basis for most of today’s solar panels — but adds a semi-transparent layer of a material called perovskite, which can absorb higher-energy particles of light. Unlike an earlier “tandem” solar cell reported by members of the same team earlier this year — in which the two layers were physically stacked, but each had its own separate electrical connections — the new version has both layers connected together as a single device that needs only one control circuit.

The new findings are reported in the journal Applied Physics Letters by MIT graduate student Jonathan Mailoa; associate professor of mechanical engineering Tonio Buonassisi; Colin Bailie and Michael McGehee at Stanford; and four others.

“Different layers absorb different portions of the sunlight,” Mailoa explains. In the earlier tandem solar cell, the two layers of photovoltaic material could be operated independently of each other and required their own wiring and control circuits, allowing each cell to be tuned independently for optimal performance.

By contrast, the new combined version should be much simpler to make and install, Mailoa says. “It has advantages in terms of simplicity, because it looks and operates just like a single silicon cell,” he says, with only a single electrical control circuit needed.

One tradeoff is that the current produced is limited by the capacity of the lesser of the two layers. Electrical current, Buonassisi explains, can be thought of as analogous to the volume of water passing through a pipe, which is limited by the diameter of the pipe: If you connect two lengths of pipe of different diameters, one after the other, “the amount of water is limited by the narrowest pipe,” he says. Combining two solar cell layers in series has the same limiting effect on current.

To address that limitation, the team aims to match the current output of the two layers as precisely as possible. In this proof-of-concept solar cell, this means the total power output is about the same as that of conventional solar cells; the team is now working to optimize that output.

Perovskites have been studied for potential electronic uses including solar cells, but this is the first time they have been successfully paired with silicon cells in this configuration, a feat that posed numerous technical challenges. Now the team is focusing on increasing the power efficiency — the percentage of sunlight’s energy that gets converted to electricity — that is possible from the combined cell. In this initial version, the efficiency is 13.7 percent, but the researchers say they have identified low-cost ways of improving this to about 30 percent — a substantial improvement over today’s commercial silicon-based solar cells — and they say this technology could ultimately achieve a power efficiency of more than 35 percent.

They will also explore how to easily manufacture the new type of device, but Buonassisi says that should be relatively straightforward, since the materials lend themselves to being made through methods very similar to conventional silicon-cell manufacturing.

One hurdle is making the material durable enough to be commercially viable: The perovskite material degrades quickly in open air, so it either needs to be modified to improve its inherent durability or encapsulated to prevent exposure to air — without adding significantly to manufacturing costs and without degrading performance.

This exact formulation may not turn out to be the most advantageous for better solar cells, Buonassisi says, but is one of several pathways worth exploring. “Our job at this point is to provide options to the world,” he says. “The market will select among them.”

The research team also included Eric Johlin PhD ’14 and postdoc Austin Akey at MIT, and Eric Hoke and William Nguyen of Stanford. It was supported by the Bay Area Photovoltaic Consortium and the U.S. Department of Energy.

Source: News Office

Illustration of superconducting detectors on arrayed waveguides on a photonic integrated circuit for detection of single photons.

Credit: F. Najafi/ MIT

Toward quantum chips

Packing single-photon detectors on an optical chip is a crucial step toward quantum-computational circuits.

By Larry Hardesty


CAMBRIDGE, Mass. – A team of researchers has built an array of light detectors sensitive enough to register the arrival of individual light particles, or photons, and mounted them on a silicon optical chip. Such arrays are crucial components of devices that use photons to perform quantum computations.

Single-photon detectors are notoriously temperamental: Of 100 deposited on a chip using standard manufacturing techniques, only a handful will generally work. In a paper appearing today in Nature Communications, the researchers at MIT and elsewhere describe a procedure for fabricating and testing the detectors separately and then transferring those that work to an optical chip built using standard manufacturing processes.

Illustration of superconducting detectors on arrayed waveguides on a photonic integrated circuit for detection of single photons. Credit: F. Najafi/ MIT
Illustration of superconducting detectors on arrayed waveguides on a photonic integrated circuit for detection of single photons.
Credit: F. Najafi/ MIT

In addition to yielding much denser and larger arrays, the approach also increases the detectors’ sensitivity. In experiments, the researchers found that their detectors were up to 100 times more likely to accurately register the arrival of a single photon than those found in earlier arrays.

“You make both parts — the detectors and the photonic chip — through their best fabrication process, which is dedicated, and then bring them together,” explains Faraz Najafi, a graduate student in electrical engineering and computer science at MIT and first author on the new paper.

Thinking small

According to quantum mechanics, tiny physical particles are, counterintuitively, able to inhabit mutually exclusive states at the same time. A computational element made from such a particle — known as a quantum bit, or qubit — could thus represent zero and one simultaneously. If multiple qubits are “entangled,” meaning that their quantum states depend on each other, then a single quantum computation is, in some sense, like performing many computations in parallel.

With most particles, entanglement is difficult to maintain, but it’s relatively easy with photons. For that reason, optical systems are a promising approach to quantum computation. But any quantum computer — say, one whose qubits are laser-trapped ions or nitrogen atoms embedded in diamond — would still benefit from using entangled photons to move quantum information around.

“Because ultimately one will want to make such optical processors with maybe tens or hundreds of photonic qubits, it becomes unwieldy to do this using traditional optical components,” says Dirk Englund, the Jamieson Career Development Assistant Professor in Electrical Engineering and Computer Science at MIT and corresponding author on the new paper. “It’s not only unwieldy but probably impossible, because if you tried to build it on a large optical table, simply the random motion of the table would cause noise on these optical states. So there’s been an effort to miniaturize these optical circuits onto photonic integrated circuits.”

The project was a collaboration between Englund’s group and the Quantum Nanostructures and Nanofabrication Group, which is led by Karl Berggren, an associate professor of electrical engineering and computer science, and of which Najafi is a member. The MIT researchers were also joined by colleagues at IBM and NASA’s Jet Propulsion Laboratory.

Relocation

The researchers’ process begins with a silicon optical chip made using conventional manufacturing techniques. On a separate silicon chip, they grow a thin, flexible film of silicon nitride, upon which they deposit the superconductor niobium nitride in a pattern useful for photon detection. At both ends of the resulting detector, they deposit gold electrodes.

Then, to one end of the silicon nitride film, they attach a small droplet of polydimethylsiloxane, a type of silicone. They then press a tungsten probe, typically used to measure voltages in experimental chips, against the silicone.

“It’s almost like Silly Putty,” Englund says. “You put it down, it spreads out and makes high surface-contact area, and when you pick it up quickly, it will maintain that large surface area. And then it relaxes back so that it comes back to one point. It’s like if you try to pick up a coin with your finger. You press on it and pick it up quickly, and shortly after, it will fall off.”

With the tungsten probe, the researchers peel the film off its substrate and attach it to the optical chip.

In previous arrays, the detectors registered only 0.2 percent of the single photons directed at them. Even on-chip detectors deposited individually have historically topped out at about 2 percent. But the detectors on the researchers’ new chip got as high as 20 percent. That’s still a long way from the 90 percent or more required for a practical quantum circuit, but it’s a big step in the right direction.

Source: MIT News Office